Electric field control of the magnetic state of a material could enable new low-power logic devices and nonvolatile memory cells. One of the missing ingredients has been a way to easily and rapidly control the magnetic properties of a material electrically, by applying a voltage. Previous attempts have relied on electron accumulation at the interface between a metallic magnet and an insulator, where the electrical charge can change the magnetic properties of the material, but only by a very small amount.
We show that by sandwiching an solid-state electrolyte layer between a magnetic layer and a top electrode layer, the properties of the magnetic layer could be changed dramatically by applying a small voltage across the stack. The change is achieved through ionic transport and electrochemical reactions. The amplitude of change is much greater than that achieved through pure electronic effect. Changes in magnetic properties made in this way remain in their new state without the need for any ongoing power. These effects open the door to electrically gated spintronic devices based on materials amenable to integration with conventional semiconductor electronics.
The same techniques could be used to alter other properties of materials, such as electrical, optical or thermal properties. These properties can ordinarily be changed only through mechanical or chemical processing. The approach enables these properties to be controlled electrically, to be switched on and off.
Sara, Usama, Alex
106. M. Huang, M. U. Hasan, K. Klyukin, D. Zhang, D. Lyu, P. Gargiani, M. Valvidares, S. Sheffels, A. Churikova, F. Büttner, J. Zehner, L. Caretta, K.-Y. Lee, J. Chang, J.-P. Wang, K. Leistner, B. Yildiz, and G. S. D. Beach, “Voltage control of ferrimagnetic order and voltage-assisted writing of ferrimagnetic spin textures,” Nat. Nanotechnol., (2021). (view pdf)
105. J. Zehner, D. Wolf, M. U. Hasan, M. Huang, D. Bono, K. Nielsch, K. Leistner, and G. S. D. Beach, “Magnetoionic control of perpendicular exchange bias,” Physical Review Materials, vol. 5, p. L061401 (2021). (view pdf)
92. M. Huang, A. J. Tan, F. Büttner, H. Liu, Q. Ruan, W. Hu, C. Mazzoli, S. Wilkins, C. Duan, J. K. W. Yang, and G. S. D. Beach, “Voltage-gated optics and plasmonics enabled by solid-state proton pumping,” Nat. Commun., 10, 5030 (2019). (view pdf)
89. A. J. Tan, M. Huang, S. Sheffels, F. Büttner, S. Kim, A. H. Hunt, I. Waluyo, H. L. Tuller, and G. S. D. Beach, “Hydration of gadolinium oxide (GdOx) and its effect on voltage-induced Co oxidation in a Pt/Co/GdOx/Au heterostructure,” Phys. Rev. Mater., vol. 3, no. 6, p. 064408, (2019). (view pdf)
84. A. J. Tan, M. Huang, C. O. Avci, F. Büttner, M. Mann, W. Hu, C. Mazzoli, S. Wilkins, H. L. Tuller, and G. S. D. Beach, “Magneto-ionic control of magnetism using a solid-state proton pump,” Nat. Mater., (2018). (view pdf)